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Why Gold–Palladium Alloys Are Better than Palladium for Hydrogen Storage
Why Gold–Palladium Alloys Are Better than Palladium for Hydrogen Storage

A research team led by The University of Tokyo investigated why alloying with gold improves hydrogen storage in palladium. The hydrogen concentration in sub-surface palladium was maximized when 0.4 monolayers of gold atoms were alloyed in the surface. DFT calculations and photoemission spectroscopy showed that gold destabilized the surface-chemisorbed hydrogen atoms, hastening their diffusion from the surface into the interior. This will aid the design of hydrogen storage materials as energy carriers and catalysts.